Evolution of chemistry and morphology during the carbonization and combustion of rice husk

Both fine carbon/silica and pure silica powders can be obtained by carbonization and combustion of rice husk under non-isothermal conditions, and the products can be used for preparation of high-quality ceramic materials. Studies on the morphology, chemical and physical characteristics of products were carried out by N₂-adsorptionmeter, SEM, XRD, FTIR, ICP-MS and EA. Results indicate that decreasing the heating rate increased the specific surface area, pore volume and pore diameter. At a heating rate of 5 °C/min, the specific surface areas of both the carbon/silica and pure silica powders were 261 and 235 m²/g, and the average pore diameters were 2.2 and 5.4 nm, respectively. The products obtained from various heating rates were all amorphous. Thermogravimetric analysis was employed to study the reaction characteristics during carbonization or combustion, indicating that decomposition process of rice husk could be divided into three temperature zones. This results of the study can also provide the important information on the recovery of biomass material from rice husk.     

Mössbauer analysis of iron phases in brown coal ash and fireside deposits

The iron phases present in an electrostatic precipitator ash, an uncooled ash deposit and a cooled superheater ash deposit from Hazelwood Power Station, Australia, burning Morwell brown coal has been examined using Mössbauer spectroscopy. The principal iron phase in the precipitator ash and the uncooled ash deposit from a hot gas offtake was calcium aluminoferrite (Ca₂Fe_{2 ? x}Al_xO₅). Minor amounts of hematite (α-Fe₂O₃) and magnetite (Fe₃O₄) were also detected in the precipitator ash. The cooled superheater ash deposit contained a (Mg, Fe, Al) oxide spinel as the primary iron phase; small quantities of hematite were also detected in this deposit close to the heat exchanger interface. The formation of these iron phases has been rationalized on the basis of the average composition of coal delivered to the power station and supplementary ash chemistry data obtained from other techniques. The evidence suggests that the calcium aluminoferrite in the precipitator ash is derived from inorganic constituents (distributed throughout the coal organic matrix) and the hematite and magnetite are of mineral origin (discrete particles).     

Synthesis and characterization of biodegradable polyethylene by graft copolymerization of starch using glucose–Ce(IV) redox system

Graft copolymerization of low‐density polyethylene (LDPE) onto starch was carried out with glucose–cerium(IV) redox initiator in an aqueous sulfuric acid medium under nitrogen atmosphere. The graft yield was influenced by various parameters like reaction time, temperature, and concentrations of acid, glucose, polyethylene (PE), starch, and initiator. A maximum graft yield of 85.66% was obtained at a temperature of 50°C and at higher concentration of starch. Effect of grafting on crystallinity, morphology, and thermal properties of modified PE has been evaluated using X‐ray diffraction, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA/DTA). Biodegradability of starch‐grafted PE has been tested applying soil‐burial test. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3229–3239, 2006     

柴油机废烟气驱动的热管LiBr制冷机的分析

工业过程中的废热排放造成了可用能的损失 ,又造成热污染和环境污染。针对一种利用热管回收废热的LiBr制冷机 ,采用柴油机烟气废热制冷实测后 ,对该系统的实测结果进行了火用分析 ,分析结果表明了这种新型废热LiBr制冷机有效利用了柴油机烟气余热 ,提高了系统的火用效率     

西石门矿盘区开采过程的三维应力分析

用崩落法开采缓倾斜中厚矿体,其底板采准巷道的稳定与否是关键。重点研究了开采线前方底板采准巷道的稳定性和应力集中情况。用三维应力分析方法给出了西石门铁矿南采区在整个开采平面上底板应力集中系数的分布,预测了开采中的顶板拉应力状况,根据计算结果,对该采区各个开采时期的应力变化进行了分析并提出了建议。     

Reductive alkylation of illinois No. 6 coal. 1H and 13C n.m.r. spectra of the 13C-enriched alkylation products

The reductive alkylation of Illinois No. 6 coal has been carried out using potassium and naphthalene in tetrahydrofuran and methyl-¹³C and butyl-1 -¹³C iodides to alkylate the resultant polyanion. The soluble products of the reductive alkylation reaction were isolated by extraction and chromatography. Proton and carbon n.m.r. spectra were recorded. The intense resonance signal at δ3.95 which appears in the proton n.m.r. spectra of Illinois No. 6 coal butylated with unenriched butyl iodide is split into a doublet by the ¹³C nuclei. Similar results were obtained for the methylation products. The chemical shift and coupling interaction establish that aryl ethers are a very important constituent of the alkylated coal. The carbon n.m.r. spectra of the coal alkylated with ¹³C-enriched alkyl iodides are intense. The resonances of the C-alkylation products appear in a single broad band with a maximum intensity in spectral regions compatible with the formation of the reductive alkylation products of certain polynuclear aromatic hydrocarbons or the base-catalysed alkylation of certain benzylic carbon atoms. The resonances of the N -alkylation products appear in two distinct bands. These resonances are tentatively assigned to amines produced as a result of reductive alkylation of heterocyclic compounds. The resonances of the 0-alkylation products appear in three distinct bands which can be assigned to alkyl aryl ethers, alkyl aryl ethers with substituents at the adjacent positions, and to alkyl carboxylates. The ratio of ethers to carboxylates in the soluble alkylation products was determined to be 7.8 for butylation and 8.0 for methylation. The Chromatographic fractions contain different amounts of C-, N-, and 0-alkylation products. This finding suggests that the coal structure is not highly uniform.     

[火用]分析环境模型及其确立原则的研究

对现有的环境模型和有关环境模型的理论进行了评述和分析，指出了确定环境模型的理论以及现有的环境模型中存在的问题，提出了比较系统的确定环境模型的理论原则。     

网吧“零点断网”自动控制策略——以华为接入交换机S3xxx系列为例

该文在分析网吧“零点断网”手工操作的复杂性和低效性基础上,提出并在华为S3xxx系列接入交换机实现了网吧“零点断网”自动控制策略,并分别以二层ACL和三层ACL作了说明。本法极大提高了“零点断网”的效率和精确性,具有极高的推广价值。     

浅析无线网现状及相关技术

无线网作为一种现代化的技术手段,随着网络信息技术的不断发展完善,在实际中的应用越来越广泛和普遍,对于无线网技术的研究与关注内容也越来越多,进行无线网现状以及相关技术的研究分析,有利于促进无线网在实际应用中的改进和提升,具有积极的作用和意义。下文将结合无线网在实际网络通信传输中的应用现状,以网络建设中的安全管理为例,对其安全保护现状以及存在的问题、解决措施等进行分析论述。